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Everything you wanted to know about nickel laterites - Stan Sudol

The last few years of the 20th century were not very kind to the nickel industry. In October and December of 1998, the LME price for nickel dipped to $1.76 a pound (US), the lowest level ever, if you factor in inflation.

The last few years of the 20th century were not very kind to the nickel industry. In October and December of 1998, the LME price for nickel dipped to $1.76 a pound (US), the lowest level ever, if you factor in inflation. The imploding Russian economy was dumping nickel on Western markets, the Asian currency crisis was annihilating economic growth and metal demand, and new lower-cost mine production was threatening to come on stream.

Of great concern to the soon to be merged Inco Ltd. and Falconbridge Ltd., was an upstart Australian company called Anaconda Nickel Ltd.
Anaconda Nickel, together with Swiss commodities house Glencore International, were building a billion-dollar mine and processing facility at Murrin Murrin, located 250 km north of Kalgoorlie in Western Australia.

Using an innovative high-pressure acid-leaching (HPAL) technology, Murrin Murrin was expected to produce 45,000 tonnes of nickel and 3,000 tonnes of cobalt annually. The production costs for the nickel were estimated to be between $0.60 and $1.25 a pound-among the lowest in the industry.

Two other smaller nickel laterite projects in Western Australian were also under construction at the same time, Centaur Mining and Exploration Ltd.'s Cawse Mine at 9,000 tonnes/year (tpa) of nickel and Preston Resources's Bulong Mine at 7,000 tpa nickel.

At the time, these three projects posed a significant threat to the traditional dominance of Inco and Falconbridge, whose nickel production costs were averaging about $1.50 a pound.

Nickel laterites are the future

Nickel can be produced from either sulphide or laterite ore. About 72 percent of the world's nickel resources are laterites found mainly in tropical locales such as Indonesia, Cuba, Brazil and New Caledonia.

The remaining 28 percent are sulphides primarily located in Canada and Russia. Australia has both sulphide and laterite nickel deposits. In 1968 laterites supplied 28 percent of global nickel demand, rising to 42 percent in 2003 and expected to increase to 51percent by 2012.

Sulphide ores are generally found hundreds of metres below surface, requiring considerable expense for underground mining infrastructure. Soft laterites are near-surface deposits, about 15 to 20 metres deep, and require only selective earth moving using truck and shovel technology.

Over geological time, laterite deposits are produced by weathering and the action of groundwater that leaves a concentration of valuable metals. The tropical wet deposits in Cuba, Indonesia and New Caledonia have higher nickel values and contain iron oxides. The dry laterites of Australia, formed over a longer period, have lower nickel content and contain more clay that poses extra processing challenges.

Laterite deposits usually contain an upper dark red zone that changes to yellow and is known as the limonite or oxide layer. The lower bright green zone contains the saprolite or silicate dominate zone. Due to the various quantities of iron, magnesium and silica in each zone, they must be processed differently to cost-effectively retrieve the nickel. In general, the limonite zone is conducive to HPAL technology while saprolite orebodies or silicate laterites have been processed with standard pyrometallurgical methods.

Nickel producer Societe Le Nickel (SLN) which is 90 percent owned by the French company Eramet, is the grandfather of saprolite operations. SLN was formed in 1880 and is the dominate producer on New Caledonia with the 60,000 tpa Doniambo smelter in the capital Noumea. The facility turns out both nickel matte and ferro-nickel.

Nickel laterite deposits were first discovered by the French civil engineer Jules Garnier, in 1864 in New Caledonia. Commercial production started in 1875 with occasional interruptions.

The New Caledonia laterites were the world's largest source of nickel until 1905 when Sudbury's enormous sulphide deposits took over and single-handedly dominated global production for the next 70 years.

Since the 1970s, Inco's Indonesian facilities at Sorowako (1977), and Falconbridge's Falcondo Mine in the Dominican Republic (1971) have used standard pyrometallurgical operations to process nickel laterites with great success.

In addition BHP Billiton built a large facility at Cerro Matoso, Colombia in 1982. The end product from these facilities is an iron-nickel alloy (ferronickel), or a high grade nickel matte.

Inco is boosting the capacity of its Indonesian operations 25 percent to 91,000 tonnes by 2009.

Historically, due to the difficulties processing limonite orebodies, most of the economically successful laterite nickel operations to date, have focused on the saprolite deposits with the chief exception of Sherritt International's Cuban Moa Bay operations, a Communist enclave where the traditional capitalist rules of profit, loss, supply and demand are all suspended.

Sherritt and Cuba

High-pressure acid-leaching (HPAL) technology is not new. It has been carried out successfully at Moa Bay, Cuba, for more than 35 years. The original process for ammonia pressure leaching of nickel concentrate was developed by Professor Frank A. Forward of the University of British Columbia for Sherritt International in 1948. Sherritt established a research group headed by Vladimir Mackiw that became internationally known for their expertise in HPAL technologies.

A refinery was built in Fort Saskatchewan, Alta., originally to process sulphide concentrate from Sherritt's mine in northern Manitoba. In 1994, Sherritt, which had been processing Cuban nickel-cobalt mixed sulphides since 1991, concluded a deal with Fidel Castro to create a vertically integrated nickel and cobalt mining, refining and marketing operation, with facilities at Moa Bay and Fort Saskatchewan. This is operated as a 50 percent (Sherritt) and 50 percent (General Nickel Co. of Cuba) joint venture.

Another hydrometallurgical method called the Caron process can also be used for limonitic ores or a mixture of limonite and saprolite.

However, there are some disadvantages and many industry professionals believe that the process is not economical with today's high cost of energy.

HPAL technology

HPAL plants require sophisticated equipment and expertise to work properly and reach full capacity. The technology basically involves processing ore in a sulphuric acid leach at elevated temperatures (up to 270ºC) and pressures (600 psi) to selectively extract the nickel and cobalt from the iron-rich ore. In most modern plants, the pressure leaching is done in titanium-lined autoclaves that resemble large metallic cigars or submarines.

Counter-current decantation is used to separate the solids and liquids.

There are various ways of separating and purifying the nickel-cobalt solution. The methods include solvent extraction, electrowinning as well as other methods currently being tested. The final products are mostly electro-nickel, nickel oxide or nickel briquettes.

Economic nightmare

Murrin Murrin was the largest of the three Western Australian projects, with plans to expand its capacity from 45,000 to 115,000 tpa nickel.

Analysts even predicted that Anaconda would become one of the world's five largest nickel producers.

What went wrong? Perhaps the biggest error besides lack of capital was that Anaconda rushed into production, to take advantage of start-up delays at Inco's Voisey's Bay project in Labrador. Anaconda bypassed the demonstration plant stage and progressed directly from laboratory to full-scale production, but the dry, clay-ridden Australian laterites proved to be more challenging than originally thought.

In addition, there were construction design flaws, engineering issues, cost escalations and the selection of poor materials that couldn't withstand the corrosive, high-temperature and high-pressure environment. Combine the above with disgruntled investors, billion-dollar lawsuits, billion-dollar losses and the shredding of corporate reputations and it's amazing that Murrin Murrin is still in operation. The operation is now making a profit, yet maintenance problems still plague the facility that has never reached it 45,000 tpa nickel capacity. (It produced 28,631 tonnes of nickel in the 2004-2005 year.)

The other two smaller Australian laterite producers went bankrupt.

There is no doubt that the three laterite projects damaged Australia's mining reputation, just as the Bre-X scandal negatively impacted Canada's standing back in 1997. However, lessons have been learned and Murrin Murrin, Bulong and Cawse have produced a generation of technocrats with laterite expertise that are in demand around the world and at other potential Australian projects that must be developed to meet expanding global demand.

In a future column I will discuss the new laterite projects.

Stan Sudol is a Toronto-based communications consultant who writes extensively on mining and Ontario issues. He can be reached at[email protected]


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